Bulletin of the Korean Chemical Society

  • 제13권3호
  • /
  • Pages.252-255
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  • 1992
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  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Syntheses and Phase-transfer Catalytic Activities of Monoazacrown Ethers

  • Shim Jae Hu (Department of Chemical Engineering, Dongguk University) ;
  • Chung Kwang Bo (Department of Chemical Engineering, Dongguk University) ;
  • Masao Tomoi (Department of Applied Chemistry, Faculty of Engineering, Yokohama National University)
  • 발행 : 1992.06.20
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초록

Preparative methods for and catalytic activities of monoaza-18-crown-6 or monoaza-15-crown-5 in the reaction of 1-bromooctane with aqueous KI or NaI were investigated. Monoazacrown ethers were prepared by debenzylation of N-benzylmonoazacrown ethers, obtained from the reaction of N-benzyldiethanolamine and oligoethylene glycol ditosylate. The phase-transfer catalytic activity of N-benzylmonoazacrown ethers was higher than that of the corresponding monoazacrown ethers.

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참고문헌

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피인용 문헌

  1. ChemInform Abstract: Syntheses and Phase-Transfer Catalytic Activities of Monoazacrown Ethers. vol.23, pp.46, 1992, https://doi.org/10.1002/chin.199246198
  2. Steric and Stereoelectronic Effects in Aza Crown Ether Complexes[1] vol.1998, pp.7, 1992, https://doi.org/10.1002/(sici)1099-0690(199807)1998:7<1379::aid-ejoc1379>3.0.co;2-9