Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Preparation and Characterization of Dinuclear and Trinuclear Metal Complexes, $[(PPh_3)_2(CO)M({\mu}-E)M(CO)(PPh_3)_2]X_2$ (M=Rh, Ir; E=Pyrazine, 4,4'-Bipyridyl, $X=SO_3CF_3$; $E=Pd(CN)_4$, $Pt(CN)_4$, X=none)

  • Ko Jaejung (Department of Chemical Education, Korea National University of Education) ;
  • Lee Myunggab (Department of Chemical Education, Korea National University of Education) ;
  • Kim Moonsik (Department of Chemical Education, Korea National University of Education) ;
  • Kang Sang Ook (Department of Chemistry, College of Natural Sciences, Korea University)
  • Published : 1992.04.20
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Abstract

Hydrocarbon solution of $(PPh_3)_2(CO)MOSO_2CF_3(M=Rh$, Ir)reacts rapidly with Pyrazine or 4,4'-bipyridyl to yield dinuclear metal complexes $[(PPh_3)_3(CO)M({\mu}-pyrazine)M(CO)(PPh_3)_2](SO_3CF_3)_2$ (I: M= RhH; III: M=Ir) or [$(PPh_3)_2$(CO)M(${\mu}$-44'-bipyridyl)M(CO)$(PPh_3)_2](SO_3CF_3)_2$, (II: M=Rh; IV: M=Ir), respectively. Compounds, I, II, III, and IV were characterized by $^1H-NMR$, $^{13}C-NMR$, $^{31}P-NMR$, and infrared spectrum. Ethanol solution of $(PPh_3)_2(CO)MOSO_2CF_3$ (M=Rh, Ir) also reacts with $(TBA)_2$M'$(CN)_4$ (M'=Pd, Pt) to yield trinuclear metal complexes [$(PPh_3)_2$(CO)dM-NCM'$(CN)_2$CN-M(CO)$(PPh_3)_2]$ (V : M=Rh, M'=Pd; VI : M=Rh, M'=Pt; VII: M=Ir, M'=Pd; VIII: M=Ir, M'=Pt). The trinuclear metal complexes V, VI, VII, and VIII are bridged by the cyanide groups. The infrared spectrum of V, VI, VII, and VIII supports the presence of the bridged cyanide and terminal cyanide group.

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References

  1. Inclusion Compounds J. L. Atwood;J. E. D. Davies;D. D. MacNicol
  2. J. Am. Chem. Soc. v.112 B. F. Hoskins;R. Robson
  3. J. Am. Chem. Soc. v.111 B. F. Hoskins;R. Robson
  4. J. Chem. Soc., Chem. Commun. v.60 B. F. Abrahams;B. F. Hoskins;R. Robson
  5. Chem. Lett. S. Nishikiori;T. Iwamoto
  6. Chem. Lett. S. Nishikiori;T. Iwamoto
  7. Chem. Lett. T. Hasegawa;S. Nisjikiori;T. Iwamoto
  8. Chem. Lett. S. Nishikiori;T. Iwamoto
  9. J. Am. Chem. Soc. v.112 M. Fujita;J. Yazaki;K. Ogura
  10. Inorg. Syn. v.11 D. Evans;J. A. Osborn;G. Wilkinson
  11. Inorg. Syn. v.11 K. Vrieze;J. P. Collman;C. T. Sears;M. Kubota
  12. J. Am. Chem. Soc. v.111 D. J. Liston;Y. J. Jee;W. R. Scheidt;C. A. Reed
  13. Inorg. Syn. v.2 J. H. Bigelow
  14. J. Am. Chem. Soc. v.90 W. R. Mason;H. B. Gray
  15. J. Organomet. Chem v.87 G. K. N. Reddy;B. R. Ramesh
  16. Indian J. Chem. Chem.Sect. A. v.15A G. K. N. Reddy;B. R. Ramesh
  17. Angew. Chem. Int. Ed. Engl. v.10 J. Peone. Jr.;L. Vaska
  18. Inorg. Chem. v.8 J. L. Burmeister;N. J. DeStefano
  19. Inorg. Chem. v.3 D. M. L. Goodgame;M. A. Hitchman
  20. The Principles of Electrochemistry D. A. MacInnes
  21. Inorg. Chem. v.12 J. S. Kritoff;D. F. Shriver
  22. Inorg. Chem. v.15 L. E. Manzer;G. W. Parshall
  23. Bull. Kor. Chem. Soc. v.7 H. M. Jeong;C. S. Chin
  24. Inorg. Chem. v.20 J. A. Abys;G. Ogar;W. M. Risen, Jr.