Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Deoxygenation of ${\beta}$-Aryl-${\alpha}$,${\beta}$-Epoxy Silanes to Vinylsilanes by Magnesium-Magnesium Halide

  • Kang, Kyung-Tae (Department of Chemical Education, Pusan National University) ;
  • Park, Chun-Yi (Department of Chemical Education, Pusan National University) ;
  • Kim, Joung-Sook (Department of Chemical Education, Pusan National University)
  • Published : 1992.02.20
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Abstract

The reactions of ${\beta}-aryl-{\alpha},{\beta}-epoxy$ silanes with magnesium bromide or magnesium iodide in the presence of excess magnesium in ether at room temperature afforded vinylsilanes in 18-100% yields. E-Vinylsilanes were predominant over Z-isomers (> 80%) regardless of the stereochemistry of ${\alpha},{\beta}-epoxy$ silanes.

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References

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