분자간 전하이동형 기능성 색소의 합성과 물성

Syntheses and Characteristics of Intermolecular Charge-Transfer Complex Dyes

  • Kim, Sung Hoon (Department of Dyeing and Finishing, College of Engineering, Kyungpook National University, Taegu 702-701, Korea) ;
  • Lee, Soon Nam (Department of Dyeing and Finishing, College of Engineering, Kyungpook National University, Taegu 702-701, Korea) ;
  • Lim, Yong Jin (Department of Dyeing and Finishing, College of Engineering, Kyungpook National University, Taegu 702-701, Korea)
  • 발행 : 1992.03.01

초록

The charge-transfer(CT) complexes derived from various donors and acceptors were evaluated as coloring matter. Dyes absorbing light in the region from the visible to the near-infrared wavelengths were synthesized. In order to determine the molar ratio of the donor to the acceptor in the CT complex in the solution, the continuous variational method was applied to each system. A 1:1 correspondence between the donor and the acceptor molecules in the CT complex in the solution is established. Color development properties in paper were examined. The longer the exposure time at constant temperature, the deeper the strength of color in paper. The strength of color at high temperature was decreased, because sublimed CT dyes in paper were migrated out side of paper.

키워드