Effect of Heat Treatment on the Nonlinear Exponents in ZnO Varistors

열처리에 따른 ZnO 바리스터의 비직선 계수의 영향

  • 안충선 (경상대학교 무기재료공학과) ;
  • 심영재 (경상대학교 무기재료공학과) ;
  • 조병두 (경상대학교 무기재료공학과)
  • Published : 1992.02.01

Abstract

Nonlinear exponents and electron trap density variations were observered in ZnO-Bi2O3-MnO2 ternary ZnO varistors as a function of heat treatment temperature. Three kinds of ZnO varistor compositions were selected; i.e. 99.0 ZnO-0.5 Bi2O3-0.5 MnO2, 98.5 ZnO-1.0 Bi2O3-0.5 MnO2, and 98.0 ZnO-1.5 Bi2O3-0.5 MnO2 in mol%. Sintering was done at 1150$^{\circ}C$ for three hours, and heat treatments were done at 500$^{\circ}C$, 700$^{\circ}C$, and 900$^{\circ}C$. When heat treated at 500$^{\circ}C$, nonlinear exponents were increased regardless of the Bi2O3 amount. Increasing heat treatment temperature above 500$^{\circ}C$ resulted in lowering nonlinear exponents. Nonlinear exponents seem to be related to the 0.17 and 0.33 eV electron traps which are possibly of intrinsic origin.

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References

  1. Jpn. J. Appl. Phys. v.10 no.6 Nonhmic Properties of ZnO Ceramics Matsuoka
  2. J. Appl. Phys. v.48 no.4 Low-temperature Electrical studies on Metal-oxide Varistors-A Clue to Conduction Mechanisms H.R. Philipp;L.M. Levinson
  3. Am Ceram. Soc. Bull. v.65 no.4 Zinc Oxide Varistors A Review L.M. Levinson;H.R. Philipp
  4. J. Apply. Phys. v.60 no.12 Bulk Electron Traps in ZnO Varnstors J.F. Cordaro;Y. Shim
  5. J Appl. Phys. v.66 no.11 Effects of Dopants on the Deep Bulk Levels in the ZnO-Bi₂O₃-MnO₂ System Youngjae Shim;James F. Condaro
  6. J Appl Phys v.66 no.11 Origin of the Pulse Response Characteristics of Zinc Oxide Varistors F.A. Modine;R.B. Wheeler;Y. Shin;J.F Cordaro
  7. Ph. D Thesis Electron Traps in Zinc Oxide Varistors Youngjae Shim
  8. Phys. Rev. B v.33 no.6 Carrier Transport Through Grain Boundaries in Semiconductors G. Blatter;F. Greuter
  9. J Appl Phys. v.63 no.11 The Depp Level Transient Spectroscopy Studies of a ZnO Varistor as a Function of Annealing A. Rohatai;S.K. Pang;T.K. Gupta;W.D. Straub
  10. J. Phys. Chem. Solids v.11 Infrared Relfectivity of Zinc Oxides R.J. Collins;Dd A. Klcinman