Alkali-Swollen Structures of Native Cellulose Fibers by X-ray Diffraction Methods

X선회절법(線回折法)에 의한 천연 셀룰로오스 섬유의 알칼리 팽윤구조(膨潤構造)

Fine and alkali-swollen structures of native cellulose fibers were investigated by x-ray diffraction methods. The results of fine structures are shown in Table 1. In meridional x-ray diffractograms, the relative intensity ratio R of (002) to (004) for cellulose I was ca. 0.05 and for regenerated cellulose it was ca. 0.45. It was considered that the transformation from cellulose I to cellulose II resulted from the packing or conformational change of cellulose chain. Finally. although cellulose I was not detected in the alkali-swollen celluloses treated for 1 hr to 24 hrs, washing and drying them resulted in the generation of considerable amounts of cellulose I and the amount decreased with increasing alkali duration.