DOI QR코드

DOI QR Code

Direct Synthesis of Trisilaalkanes

  • Il Nam Jung (Organometallic Chemistry Laboratory, Korea Institute of Science and Technology) ;
  • Gyu-Hwan Lee (Organometallic Chemistry Laboratory, Korea Institute of Science and Technology) ;
  • Seung-Ho Yeon (Organometallic Chemistry Laboratory, Korea Institute of Science and Technology) ;
  • Mi-Yeon Suk (Organometallic Chemistry Laboratory, Korea Institute of Science and Technology)
  • Published : 1991.08.20

Abstract

A series of trisilaalkanes has been prepared in high yields by the direct reaction of ${\alpha}$ -chloromethylsilanes with metallic silicon in the presence of copper catalyst using the stirred reactor equipped with a spiral band agitator at the carefully controlled temperature between $280^{\circ}C$ and $340^{\circ}C.$ Disilaalkane compounds were obtained as the minor products. Cadmium was found to be a good promotor for the reactions, while zinc was an inhibitor.

Keywords

References

  1. Organohalosilanes, Precursors to Silicones R. J. H. Voorhoeve
  2. Zh. Obshch. Khim. v.26 A. D. Petrov;S. I. Sahykh-Zade;E. A. Chernyshev;V. F. Mironov
  3. Zh. Obshch. Khim. v.42 V. F. Mironov;T. K. Gar;E. A. Buyakov
  4. Synthesis of Silicon Monomers A. D. Petrov;B. F. Mironov;V. A. Ponomarenko;E. A. Chernyshev
  5. Rec. Trav. Chim. v.82 R. J. H. Voorhoeve;J. C. Vlugter
  6. Coll. Czech. Chem. Comm. v.26 J. Koklik;V. Bazant
  7. U.S. Patent 2,389,931 C. E. Reed;J. T. Coe
  8. Chem. Techn. v.10 H. Grohm;R. Paudert
  9. U.S. Patent 2,449,821 J. E. Sheller;J. L. Davis
  10. J. Gen. Chem. U.S.S.R. v.27 A. L. Klebamskii;V. S. Fikhtengolts
  11. Conf. Acad. Lincei. Alta Tech. Chim. v.1961 J. C. Vlugter;R. J. H. Voorhoeve
  12. J. Catalysis v.4 R. J. H. Voorhoeve;J. C. Vlugter
  13. J. Am. Chem. Soc. v.70 B. A. Bluestein
  14. U.S.S.R. Patent 394,378 V. F. Mironov;T. K. Gar;V. D. Sheludyakov;A. A. Buyakov;V. I. Andreev;I. N. Petrova
  15. Il Nam Jung
  16. Alcan, Union

Cited by

  1. ChemInform Abstract: Direct Synthesis of Trisilaalkanes. vol.23, pp.7, 1991, https://doi.org/10.1002/chin.199207213
  2. In situ study of the formation of SiC thin films on Si(111) surfaces with 1,3-disilabutane: Adsorption properties and initial deposition characteristics vol.18, pp.4, 1991, https://doi.org/10.1116/1.582470
  3. Epitaxial growth of cubic SiC thin films on silicon using single molecular precursors by metalorganic chemical vapor deposition vol.19, pp.4, 2001, https://doi.org/10.1116/1.1379321
  4. Synthesis of Isopropyldichlorosilane by Direct Process vol.28, pp.10, 2007, https://doi.org/10.5012/bkcs.2007.28.10.1661