Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Direct Synthesis of Trisilaalkanes

  • Il Nam Jung (Organometallic Chemistry Laboratory, Korea Institute of Science and Technology) ;
  • Gyu-Hwan Lee (Organometallic Chemistry Laboratory, Korea Institute of Science and Technology) ;
  • Seung-Ho Yeon (Organometallic Chemistry Laboratory, Korea Institute of Science and Technology) ;
  • Mi-Yeon Suk (Organometallic Chemistry Laboratory, Korea Institute of Science and Technology)
  • Published : 1991.08.20
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Abstract

A series of trisilaalkanes has been prepared in high yields by the direct reaction of ${\alpha}$ -chloromethylsilanes with metallic silicon in the presence of copper catalyst using the stirred reactor equipped with a spiral band agitator at the carefully controlled temperature between $280^{\circ}C$ and $340^{\circ}C.$ Disilaalkane compounds were obtained as the minor products. Cadmium was found to be a good promotor for the reactions, while zinc was an inhibitor.

Keywords

References

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  1. ChemInform Abstract: Direct Synthesis of Trisilaalkanes. vol.23, pp.7, 1991, https://doi.org/10.1002/chin.199207213
  2. In situ study of the formation of SiC thin films on Si(111) surfaces with 1,3-disilabutane: Adsorption properties and initial deposition characteristics vol.18, pp.4, 1991, https://doi.org/10.1116/1.582470
  3. Epitaxial growth of cubic SiC thin films on silicon using single molecular precursors by metalorganic chemical vapor deposition vol.19, pp.4, 2001, https://doi.org/10.1116/1.1379321
  4. Synthesis of Isopropyldichlorosilane by Direct Process vol.28, pp.10, 2007, https://doi.org/10.5012/bkcs.2007.28.10.1661