Synthesis and Shape Control of Calcium Carbonate Fine Powders by Liquid-Gas Reaction Method

액상-기상 반응법에 의한 탄산칼슘 미분말의 합성과 형상제어

  • 민경소 (한양대학교 무기재료공학과) ;
  • 최상흘 (한양대학교 무기재료공학과)
  • Published : 1991.03.01

Abstract

Calcium carbonate fine powders were synthesized by blowing CO2 gas in CaO or Ca(OH)2 suspension, and the shapes of powders obtained were examined for each synthetic condition. When water was used as a solvent, ultrafine calcite powders with the average size of∼0.03$\mu\textrm{m}$ were obtained. When synthesized using methanol as a solvent, amorphous phase and spherical vaterite phase were obtained by suction filtering and non-filtering, respectively. Reaction did not occured in ethanol medium, but spherical vaterite phase was obtained by adding ethylene glycol in ethanol.

Keywords

References

  1. Mat. Sci. Eng. v.44 no.1 Basic Research Needs on High Temperature Ceramics for Energy Applications H.K. Bowen
  2. Ceramis Bulletin v.68 no.5 Powder Synthesis Research at CAMP S. K. Ellis;E.P. Mcnamara Jr.
  3. J. Am. Ceram. Soc. v.72 no.1 Powder Processing Science and Technology for Increased Reliability F.F. Lauge
  4. Gypsum & Lime no.228 Characteristics of Powder Particle M. Chikazawa;T. Takei
  5. Gypsum & Lime no.198 Characteristics of some Inorganic Fillers and Their Effects on Composite Materials with Thermoplastics Y. Tsuruta
  6. Nippon Kagaku Kaishi no.7 Synthesis and characteristics of Amorphous Calcium Carbonate T. Yasue;A. Mamiya;Y. Takahashi;R. Tsukisaka;Y. Arai
  7. Gypsum & Lime no.198 Pigment and Filler Y. Toda;K. Hashimoto
  8. Gypsum & Lime no.198 Fillers for Paper-Properties and Analysis of Several Fillers in Paper K. Amita;H. Matsui;Y. Ono;G. Hashizume
  9. Gypsum & Lime no.91 The Effect of the Initial Reaction between Milky Lime and Carbon Dioxide Gas on the Crystal of Calcium Carbonate H. Miki
  10. Gypsum & Lime no.196 Synthesis of basic CaCO₃ from the Reaction of the System Ca(OH)₂-H₂O-CO₂ H. Yamada;N. Hara
  11. Chem. Eng. Sci. v.28 no.825 V.A. Juvekar;M.M. Sharma
  12. American Chemical Society v.1 Solubilities of Inorganic and Metal Organic Compounds(4th Edition) A. Sedell
  13. Nippon Kagaku Kaishi no.9 Synthesis and Characteristics of Fiberous Gypsum T. Yasue;Y. Kojima;Y. Arai
  14. 石膏 石灰 便覽 石膏 石灰 硏究會 (編.)