The formation of Mn-ferrite by electrolysis

전해법에 의한 Mn-ferrite 생성

The formation of managanese ferrite has been performed to investigate some properties according to the variation of compositions, pH, current density by electrolysis. It has been found that the amount of oxidized weight of anode were increased with increasing current density. The amount of oxidized weight of anode were most in pH10. As the result of X-ray diffraction Mn Fe2O4 crystal composition in pH13. When the particles of Mnx Fe3-x O4 were heated at 30$0^{\circ}C$, it has been shown typical MnFe2O4(JCPDS Card No. 10-319) in X-1 composition. As the result of SEM observation, the size of MnFe2O4 particles were about 0.1$\mu\textrm{m}$, the shape of particles were spherical type. According to the above mentioned experimental condition, 0.1-0.5$\mu\textrm{m}$ sub-micron particles of manganese ferrite were formed from the wasted manganese dry cell, through washing longrightarrow reduction longrightarrow electrloysis.