Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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The Synthesis of Pyrimidine Derivatives Containing H-Chelate

H-킬레이트가 있는 피리미딘 유도체들의 합성

  • 김정환 (영남대학교 이과대학 화학과) ;
  • 서정협 (영남대학교 이과대학 화학과)
  • Published : 19901100
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Abstract

Bis (4,6-dichloropyrimidine-5-yl) alkanes as the frame of "intramolecular electronic energy transfer" system have been synthesized and the H-chelates of $\alpha$-(4-cyanomethylquinoline-6-chloropyrimidine-5-yl)-$\omega$-(4,6-dichloropyrimidine-5-yl) alkanes have been synthesized from bis (4,6-dichloropyrimidine-5-yl) alkanes and 2-cyanomethylquinoline. The structures of the compounds have been studied by spectral methods.

분자내에서의 전자에너지 전달시스템의 골격으로서 Bis (4,6-dichloropyrimidine-5-yl) alkanes류를 합성하였으며, 이화합물과 2-cyanomethylquinoline을 반응시켜 $\alpha$-(4-cyanomethylquinoline-6-chloropyrimidine-5-yl)-$\omega$-(4,6-dichloropyrimidine-5-yl) alkanes의 H-chelate를 합성하였다. 이들 화합물에 대한 구조는 분광학적인 방법으로 연구하였다.

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