Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Electron Paramagnetic Resonance Study of Bis(N-methyl-2-amino-1-cyclopentenedithiocarboxylato)Copper (II)

  • Woo-Seong Kim (Department of Chemistry, Pusan National University) ;
  • Young-Inn Kim (Department of Chemical Education, Pusan National University) ;
  • Sung-Nak Choi (Department of Chemistry, Pusan National University)
  • Published : 1990.04.20
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Abstract

The electron paramagnetic resonance (EPR) spectrum of the copper (II) complex with the 2-methylamino-1-cyclo-pentene-1-dithiocarboxylate (acdc) anion, $Cu(N-CH_3acdc)_2$ has been studied in the diamagnetic host lattices afforded by the corresponding divalent nickel, zinc, cadmium and mercury complexes. EPR parameters of the complex support the exclusive use of sulfur atoms by the ligand in metal binding. A combination of host lattice structure and covalency effects can be account for the observed spin-Hamiltonian parameters.

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  1. EMR Study of Bis(benzene-dithiocarboxylato)copper(II) Complex in Solution and Magnetically Diluted in Different Host Lattices vol.621, pp.4, 1990, https://doi.org/10.1002/zaac.19956210434