Bulletin of the Korean Chemical Society
- Volume 11 Issue 2
- /
- Pages.140-143
- /
- 1990
- /
- 0253-2964(pISSN)
- /
- 1229-5949(eISSN)
DOI QR Code
Selective Synthesis of N-(Cyclohexylmethyl)-N-alkylamines from Primary Amines and Pimelaldehyde using Tetracarbonylhydridoferrate, $HFe(CO)_4^\;-$ , as a Reducing Agent
- Sang Chul Shim (Department of Industrial Chemistry, Kyungpook National University) ;
- Young Gil Kwon (Department of Industrial Chemistry, Kyungpook National University) ;
- Chil Hoon Doh (Department of Industrial Chemistry, Kyungpook National University) ;
- Byung Won Woo (Department of Industrial Chemistry, Kyungpook National University) ;
- Jin Ook Baeg (Department of Industrial Chemistry, Kyungpook National University) ;
- Hong Seok Kim (Department of Industrial Chemistry, Kyungpook National University) ;
- Tae Jeong Kim (Department of Industrial Chemistry, Kyungpook National University) ;
- Dong Ho Lee (Department of Industrial Chemistry, Kyungpook National University) ;
- Young Woo Kwak (Department of Industrial Chemistry, Kyungpook National University) ;
- Jin Soon Cha (Department of Industrial Chemistry, Kyungpook National University) ;
- Hyung Soo Lee (Department of Industrial Chemistry, Kyungpook National University) ;
- Jae Kook Uhm (Department of Industrial Chemistry, Kyungpook National University) ;
- Young Bae Park (Department of Industrial Chemistry, Kyungpook National University)
- Published : 1990.04.20
Abstract
Ethanolic tetra carbonylhydridoferrate solution combined with dialdehyde (no of carbon; 4,5,6) is very efficient for the selective transformation of amino group into N-heterocyclic compound. However, a large variety of both aliphatic and aromatic amines react with the ferrate-pimelaldehyde at room temperature under an atmospheric pressure of carbon monoxide to give the corresponding N-(cyclohexylmethyl)-N-alkyiamine derivatives in moderate yields instead of the corresponding N-substituted perhydroazocine derivatives.
Keywords