한국염색가공학회지 (Textile Coloration and Finishing)
- 제2권3호
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- Pages.26-35
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- 1990
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- 1229-0033(pISSN)
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- 2234-036X(eISSN)
Mono-sodium ethylene glycolate에 의한 Poly(ethylene terephthalate) Film의 분해반응에 관한 연구
Study on Decomposition Reactions of Poly(ethylene terephthalate) Films Treated with Mono-sodium Ethylene Glycolate
- Cho, Hwan (Department of Textile Engineering, Yeungnam University, Gyongsan) ;
- Huh, Man-Woo (Department of Textile Engineering, Kyungpook Sanup University, Taegu) ;
- Cho, In-Sul (Department of Textile Engineering, Yeungnam University, Gyongsan) ;
- Cho, Kyu-Min (Hankook Yeumkong, 1217, Cheem San-Dong, Taegu) ;
- Yoon, Hung-Soo (Department of Textile Engineering, Kyungpook Sanup University, Taegu)
- 발행 : 1990.09.01
초록
This study was carried out with the view of fundamental investigating to improve the tactile and the hygroscopicity of Poly(ethylene Terephthalate) (PET)fibers. Mono-sodium ethylene glycolate in ethylene glycol (MSEG-EG) solution was prepared and PET films were treated with it. The following conclusions were obtained. When PET films were decomposed in MSEG-EG solution, decomposition rate constant showed an exponential relationship with treating temperature; activition energy was 23.30 Kcal/mol, activation enthalpy was 22.52~22.60 Kcal/mol and activation entropy was -29.20~ -29.41 e.u. On the basis of the results obtained above and structure identification of decomposition products, it was found that the decomposition reaction proceeded through ester interchange reaction.
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