Textile Coloration and Finishing (한국염색가공학회지)

The Korean Society of Dyers and Finishers (한국염색가공학회)
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Fine Structural Change of PET Film Treated with Hydrazine Hydrate in Methanol

Hydrazine/Methanol 처리에 의한 PET Film의 미세구조의 변화

  • Sung, Woo-Kyung (Department of Textile Engineering, College of Engineering, Pusan National University, Pusan 609-735) ;
  • Cho, Hyun-Hok (Department of Textile Engineering, College of Engineering, Pusan National University, Pusan 609-735) ;
  • Kim, Kyung-Hwan (Department of Textile Engineering, College of Engineering, Pusan National University, Pusan 609-735)
  • Published : 1990.06.01
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Abstract

In order to investigate the fine structural changes of poly (ethylene terephthalate) film by hydrazinolysis, PET was treated with hydrazine hydrate in methanol at $30^{\circ}C$ for various times. Initially apparent crystallite size and degree of orientation are increased and then, gradually decreased with hydrazinolysis. According to thermoluminescence measurement, trap site decreased by dissolution and then gradually increased with growth of defect in structure. Maximum peak temperature of tan and dynamic loss modulus E" upon hydrazinolysis shifted to the lower temperature in the progress of hydrazinolysis.ysis.

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