Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
권호 표지

A Study on the Ceria Stabilized Tetragonal Zirconia Polycrystals(Ce-TZP)(III) : Effect of Al2O3 Addition on the Mechanical Properities and Microstructures of Ce-TZP

CeO2안정화 정방정 Zirconia 다결정체(Ce-TZP)에 관한 연구(III) : Ce-TZP의 기계적성질 및 미세조직에 미치는 Al2O3첨가의 영향

  • 김문일 (연세대학교 금속공학과) ;
  • 박정현 (연세대학교 요업공학과) ;
  • 강대석 (연세대학교 금속공학과) ;
  • 문성환 (연세대학교 요업공학과) ;
  • 안계원 (한국 뉴세라믹스 연구소)
  • Published : 1990.01.01
Download PDF
⟨ Previous Next ⟩

Abstract

Effect of Al2O3 addition on the mechanical properties and microstructure of Ce-TZP were studied. 12, 14, 16Ce-TZP containing 0-40wt% Al2O3 were prepared by sintering at 155$0^{\circ}C$ for 2h. in air. Density, linear shrinkage, bending strength, Vickers hardness, microstructuer and the amount of stress induced phase transformation were examined. Vickers hardness increased linearly with increasing amounts of Al2O3. The amount of transformation and fracture toughness decreased linearly with increasing amount of Al2O3. Linear shrinkage and relative density decreased with increasing Al2O3 content in all composition of Ce-TZP. Grain growth of Ce-TZP was inhibited by Al2O3 dispersion and fracture mode of Ce-TZP/Al2O3 composites transformed from intergranular to transgranular fracture as the amount of Al2O3 increased. TEM observation revealed that Al2O3 particles were located mainly at grain boundaries of ZrO2.

Keywords

References

  1. J. Mater. Sci. v.13 Effect of Stress Induced Phase Transformation on the Properties of Polycrystaline Zirconia Containing Metastable Tetragonal Phase T.K. Gupta;F.F. Lange;J.H. Bechtold
  2. J. Am Ceram. Soc. v.69 no.8 Mechanical Properties of Toughened ZrO₂-Y₂O₃Ceramics T. Masaki
  3. Advances in Ceramics(Vol.24) Strength and Fracture Toughness of Y-TZP, Ce-TZP, Y-TZP/Al₂O₃, and Ce-TZP/Al₂O₃ K. Tsukuma;T. Takahata;M. Shiomi;S. Somiya(ed.);N. Yamamoto(ed.);H. Hanagida(ed.)
  4. J. Am. Ceram. Soc. v.69 no.3 Stress-Induced Transformation and Plastic Deformation for Y₂O₃-Containing Tetragonal Zirconia Polycrystals M. Matsui;T. Soma;I. Oda
  5. ibid. v.71 no.3 Aging behavior of Ceria-Stabilized Tetragonal Zirconia Polycrystals R.L.K. Matsumoto
  6. Am. Ceram. Soc. Bull. v.64 no.10 Transformation of Ceria-Doped Tetragonal Zirconia Polycrystals by Annealing in Water T. Sato;M. Shimada
  7. J. Am. Ceram. Soc. v.72 no.5 Postsintering Hot Isostatic Pressing of Ceria-Doped Tetragonal Zirconia/Alumina Composites in an Argon-Oxygen Gas Atmosphere T. Sato;Endo;M. Shimada
  8. ibid. v.67 no.6 Phase Analysis in Ziconia System R. C. Garvie;P.S. Nicholson
  9. ibid. v.67 no.6 Calibration Curve for Quantitative Analysis by X-ray Diffraction H. Toraya;M. Yoshimura;S. Somiya
  10. Fracture Mechanics Applied to Brittle Materials. Use of Indentation Fracture to Determine Fracture Toughness R.H. Marion
  11. Trans. AIME v.180 Some Factors Affecting the Rate of Grain Growth in Metals[70, 30 Brsaa] C Zener;J.E. Burke
  12. J. Phys Chem. v.69 no.4 The Occurrence of Metastable Tetragonal Zirconia as a Crystallite Size Effect R C. Garvie