Textile Science and Engineering (한국섬유공학회지)

The Korean Fiber Society (한국섬유공학회)
권호 표지

Syntheses of Oxime Derivatives and Polymers Containing Oxime Groups and Their Photosensitive Characteristics (II)

옥심 유도체 및 옥심기를 가지는 고분자의 합성과 합성물의 감광특성 (II)

  • Kim, Dae-Jin (Dept. of Textile Eng., College of Eng., Seoul National University) ;
  • Hong, Sung-Il (Dept. of Textile Eng., College of Eng., Seoul National University)
  • 김대진 (서울대학교 공과대학 섬유공학과) ;
  • 홍성일 (서울대학교 공과대학 섬유공학과)
  • Published : 1990.09.01

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Abstract

Benzophenoneoxime(BZPO), ethyloximinocyanoacetate(EOCA), and terephthaldio- xime(TPDO) were synthesized from benzophenone, ethylcyanoacetate, and terephthalaldehyde, respectively. Oxime derivatives were synthesized from 6ximes with benzoylchloride, toluoylchlo-ride, anisoylchloride, ethylchlorocarbonate, and acetylchloride. And oxime monomer, benzophe-none-g-methacryloyloxime (BZMO), was synthesized from methacrylolychloride with BZPO. Photodegradation of oxime derivatives was carried out by the irradiation of W light in which the free radicals, produced during the photodegradation, could initiate vinyl monomer. The relative decomposition efficiency of oxide derivatives was estimated by comparing UV absorbance decreasing at Lmax in function of irradiation time. In addition, polymers containing oxime ester in pendant group, p(BZMO- MMA), were photografted with vinyl monomer. The graft yield of polymers increased with the mole fraction of BZMO.

Keywords

References

  1. ACS Advanced in Chemistry Series 218 Electronic and Photonic Applications of Polymers M.J.Bowden;S.R.Turmer
  2. ACS Symposium Series 219 Introduction to Microlithography L.F.Thompson;C.G.Wilsin;M.J.Bowden
  3. Enycyclopedia of Polymer Science and Technology v.9 R.W.Blevins;R.C.Daly;S.R.Turner
  4. Solid State Tech. v.30 A.S.Oberai
  5. Polym. Eng. Sci. v.29 no.13 M.J.O'Brien
  6. Polym. Eng. Sci. v.29 no.13 T.Yamaoka;M.Nishiki;K.Koseki;M.Koshiba
  7. Polym. Eng. Sci. v.29 no.14 M.Koshiba;M.Murata;Y.Harita;Yamaoka
  8. Proc. SPIE v.1086 H.Ito;L.A.Pederson;K.N.Chiong;S.Sonchik;C.Tsai
  9. Proc. SPIE v.1086 J.W.Thackeray;G.W.Orsula;E.K.Pavelchek;D.Canistro;L.E.Bogan;A.K.Berry;K.A.Graziano
  10. J. Electrochem. Sci. v.135 no.2 T.R.Pampalone;F.A.Kuyan
  11. J. Appl. Polym. Sci. v.2 L.M.Minsk;J.G.Smith;W.P.Van Deusen;J.F.Wright
  12. J. Polym. Sci. Polym. Chem. Ed. v.10 H.Tanaka;Y.Sato
  13. J. Appl. Polym. Sci. v.27 C.Azuma;K.Samui;N.Ogata
  14. Polymer v.18 Y.Yanaoka;K.Ueno;T.Tsunoda;K.Torige
  15. Macromolecules v.1 G.H.Hartley;J.E.Guillet
  16. J. Polym. Sci. Polym. Chem. Ed. v.15 W.Kawai
  17. Macromolecules v.4 Y.Amerik;J.E.Guillet
  18. Macromolecules v.5 F.J.Golemba;J.E.Guillet
  19. Polymer v.8 C.David;W.Dernarteau;G.Gewskens
  20. J. Polym. Sci. Polym. Chem. Ed. v.15 C.C.Petropoulos
  21. 高分子論文集 v.37 田中秀明;小林力夫;小水秀男
  22. J. Appl. Polym. Sci. v.26 W.C.Studhey;C.W.Roberts
  23. Macromolecules v.9 H.Hiraoka
  24. Macromolecules v.10 H.Hiraoka
  25. J. Polym. Sci. Polym. Chem. Ed. v.56 J.V.Crivello;J.H.W.Lam
  26. Macromolecules v.10 J.V.Crivello;J.H.W.Lam
  27. Tetrahedron Lett. no.3 J.Sato;H.Obase
  28. Bull. Chem. Soc. Japan v.49 H.Ohta;K.Tokumaru
  29. Polym. J. v.12 T.OTa;Y.Mori;M.Tanaka;H.Tamai;S.Masuda
  30. J. Org. Chem. v.26 L.Guy Donaruma
  31. J. Polym. Sci. Polym. Chem. Ed. v.15 M.Tsunooka;K.Kotera;M.Tanaka
  32. Modern Plastics v.66 no.8 R.V.Wilder
  33. Orgranic Synthesis, Collective Volume Ⅱ v.Ⅱ A.Lachman
  34. 한국섬유공학회지 v.25 金大進;張城勳;洪性一