Nylon6/열방성 액정 폴리에스터 블렌드

Blends of Nylon 6 with Thermotropic Liquid Crystalline Polyester

  • 발행 : 1990.09.01

초록

Blend of nylon 6 with thermotropic liquid crystalline polymer(LCP) were prepared by melt bleriding, and filaments were obtained by extruding the blends with capillary rheometer. Scanning electron microscopy revealed that fibrils of LCP were oriented along fiber axis. The increase of crystallization temperature of nylon in nylon 6/LCP blend is due to the highly oriented LCP fibrils acting as nuclei for the formation of nylon 6 crystals. The optical texture of nylon 6/LCP melt shows two phase system at 295$^{\circ}C$. Tensile modulus and yield strength increased markedly with increasing LCP content in nylon 6hcp filament. Storage modulus of nylon 6/LCP filament is higher than that of nylon 6. The improved properties might be achieved due to the fibril-reinfor- cod morphology.

키워드

참고문헌

  1. Man-Made Fiber R.W.Moncrieff
  2. Chemical Processing of Fibers and Fabrics v.2 M.Lewin;S.B.Sello
  3. Chemical Aftertreatment of Textiles H.Mark;N.S.Wooding;S.M.Altlas
  4. Fiber Chemistry M.Lewin
  5. The Chemistry and Technology of Cellulosic Copolymers A.Hebeish;J.T.Guthrie
  6. Introduction to Spectroscopy D.L.Pavia;G.M.Lampman;G.S.Kriz
  7. J. Appl. Polym. Sci. v.29 J.D.Keitz;J.W.Barlow;D.R.Paul
  8. Polym. Eng. Sci. v.22 M.T.Show
  9. Polymer Blends v.2 D.R.Paul;S.Newman
  10. Polymer-Polymer Misibility O.Olasbisi;L.M.Robeson;M.T.Show
  11. Thermal Characterization of Polymeric Materials E.A.Turi
  12. Encyclopedia of Polymer Science and Engineering(2nd Ed.) v.12 D.R.Paul;J.W.Barlow;H.Keskkular