한국환경농학회지 (Korean Journal of Environmental Agriculture)
- 제8권2호
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- Pages.136-141
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- 1989
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- 1225-3537(pISSN)
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- 2233-4173(eISSN)
Oxalylchloride를 이용한 Sulfonylurea계 유도체 합성에 관한 연구
Synthesis of Sulfonylurea Derivatives by Oxalylchloride
- Kyung, Suk-Hun (Dept. of Agricultural Chemistry, Kon-Kuk University) ;
- Tak, Yoon-Heung (Dept. of Agricultural Chemistry, Kon-Kuk University)
- 발행 : 1989.12.30
초록
Sulfonylurea계 화합물의 합성에 필요한 sulfonylisocyanate는 sulfonamide에
An alternative method for the synthesis of sulfonylurea derivatives, some of which considered to be a new recommendable herbicides, with oxalylchloride was investigated. Sulfonamides read with oxalylchloride to sulfonyloxamoylchlorides, which convert easily under pyrolysis to sulfonylisocyanates. The isocyanates react further with amines to yield corresponding sulfonylurea derivative quantitatively.
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