Reduction of Aromatic Nitro Group by Activated Cu-Zn-$NH_2NH_2{\cdot}H_2O$ in Ethanol

활성화시킨 Cu-Zn 과 히드라진을 이용한 방향족 니트로 화합물의 환원반응

  • Byung Hee Han (Department of Chemistry, College of National Science, Chungnam National University) ;
  • Dae Hyun Shin (Department of Chemistry, College of National Science, Chungnam National University) ;
  • Hyun Ro Lee (Department of Chemistry, College of National Science, Chungnam National University)
  • 한병희 (충남대학교 자연과학대학 화학과) ;
  • 신대현 (충남대학교 자연과학대학 화학과) ;
  • 이현노 (충남대학교 자연과학대학 화학과)
  • Published : 1989.12.20

Abstract

Activated Cu-Zn by the reaction of aqueous cupric sulfate and excess Zn showed the exceptional catalytic activity for the reduction of aromatic nitro compounds to the corresponding amino compounds in the presence of hydrazine monohydrate in ethanol. But, aliphatic nitro compounds were not reduced to the amino compounds.

황산구리 수용액에 과량의 아연을 반응시켜 만든 구리-아연은 히드라진 존재하에서 방향족 니트로 화합물을 아미노 화합물로 환원시키는데 좋은 촉매작용을 보여주었다. 그러나 지방족 니트로 화합물의 환원반응은 진행되지 않았다.

Keywords

References

  1. Org. Reactions v.4 D. Todd
  2. Bull. Kor. Chem. Soc. v.6 no.4 D. H. Shin;B. H. Han
  3. Chem. Rev. v.65 A. Furst;R.C. Berlo;S. Hooton
  4. Tet. Lett. A. G. M. Willems;R. R. Eck;U. K. Pandit;H. O. Huisman
  5. J. Amer. Chem. Soc. v.81 V. Georgian;R. Harrison;N. Gubisch
  6. Tet. Lett. v.21 H. J. Koeners;J. Verhoeven;J. H. van Boom.
  7. J. Org. Chem. v.38 J.E. Gordon;V.S.K. Chang
  8. Tet. Lett. v.23 K. K. Ogilvie;M. J. Nemer;G.H. Hakimelahi;Z.A. Proba;M. Lucas
  9. Chem. Ber. v.26 R.V. Rothenburg
  10. Chem. Ber. v.B62 M. Busch;K. Schulz
  11. Tetrahedron Lett. v.26 no.50 B. H. Han;D. H. Shin;S. Y. Cho
  12. Bull. Kor. Chem. Soc. v.6 no.5 B. H. Han;D. H. Shin;S. Y. Cho
  13. Daehan Hwahak Hwoejee B. H. Han;D. H. Shin;H. R. Lee
  14. Chungnam J. Science v.12 no.1 B. H. Han;M. G. Baek
  15. Modern Experimental Organic Chemistry R. M. Roberts;J. C. Gilbert;L. B. Rodewald;A. S. Wingrove
  16. Synthesis N. R. Ayyangar;A. G. Lugade;P. V. Nikrad;V. K. Sharma
  17. J. Chem. Soc., Perkin I I. D. Entwistle;A. E. Jackson;R. A. W. Johnstone;R. P. Telford
  18. Chem. Lett. T. Hirashima;O. Manabe
  19. Chem. Lett. A. Osuka;H. Shimizu;H. Suzuki
  20. Tet. Lett. v.25 S. Ram;R. E. Ehrennkaufer
  21. J. Org. Chem. v.36 no.6 R. O. Hutchins;D. W. Lamson;L. Rua;C. Milekski;B. Naryanoff
  22. J. Am. Chem. Soc. v.99 H. Abbayes;H. Alper
  23. J. Am. Chem. Soc. v.100 K. Cann;T. Cole;W. Selegeir;R. Pettit
  24. J. Mol. Catal. v.12 K. Kaneda;N. Hirak;T. Imanaka;S. Teranishi
  25. Chem. Lett. T. Okano;K. Fujiwara;H. Konishi;J. Kjii
  26. Chem. Lett. Y. Watanabe;Y. Tsuji;T. Ohsumi;R. Takeuchi
  27. Inorg. Chim. Acta. v.131 no.1 D. Nigel;M. William
  28. Tetrahedron Lett. v.29 no.6 D. Huber;G. Anderman;G. Leclerc
  29. Tetrahedron Lett. v.25 no.8 F. D. Bellamy;K. Ou
  30. J. Chem. Soc. Chem. Commun. H. Inoue;M. Shirai;E. Haruki
  31. Tetrahedron Lett. v.30 no.2 K. Mukanti;Y. V. Subba Rao;B.M. Choudary
  32. Bull. Kor. Chem. Soc. v.10 B. H. Han;D. H. Shin;H.R. Lee;B. H. Ro
  33. Org. Synthesis G. S. Hiers;F. D. Hager
  34. Daehan Hwahak Hwoejee v.30 no.1 D. H. Shin;B. H. Han;S.Y. Cho
  35. Daehan Hwahak Hwoejee v.32 no.6 H. R. Lee;E. S. Ryoo;D. H. Shin;B. O. Ro
  36. Tet. Lett. v.26 J. O. Osby;B. Ganem