지시약의 등흡광점을 이용한 용액의 pH 측정

pH Measurement Using Isosbestic Point of Indicator

  • 최원형 (慶聖大學校 理科大學 化學科) ;
  • 허호장 (慶聖大學校 理科大學 化學科)
  • Won-Hyung Choi (Department of Chemistry, Kyung Sung University) ;
  • Ho-Jang Hur (Department of Chemistry, Kyung Sung University)
  • 발행 : 1989.04.20

초록

지시약 메틸레드 용액을 시료용액에 첨가하고 지시약의 산형의 최대흡수파장과 염기형의 최대 흡수파장 및 등흡광점에서 이 시료액 흡광도를 측정하였다. 이를 측정한 흡광도로부터 이 용액의 pH를 계산하였다. 등흡광점에서 흡광도 범위를 0.1내지 0.3으로 유지하고 시료용액의 pH가 $pK_I{\pm}1$내에서, pH측정오차는 ${\pm}$0.08pH 단위 이내이었다.

The methyl red stock solution was added to sample solution and the absorbance values of this solution were measured at the maximum absorption wavelengths of the acidic form, the basic form, and the isosbestic point of the indicator. From the measurements of absorbance, the pH of this solution was calculated. The range of absorbance at the isosbestic point was maintained within 0.1 ${\sim}$ 0.3. The error of pH measurement was within ${\pm}0.08$ pH unit in the pH range of sample solution of $pK_I{\pm}1$.

키워드

참고문헌

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