Studies on the Fluorescence of $Eu^{3+}\;and\;Tb^{3+}$ in Lanthanum Oxychloride

염화산화란탄에서 유로퓸(III) 과 테르븀(III)의 형광에 관한 연구

  • Young Gu Ha (Department of Chemistry, Seoul National University) ;
  • Taesam Kim (Korea Institute of Energy and Resoures)
  • 하영구 (서울대학교 자연과학대학 화학과) ;
  • 김태삼 (한국동력자원연구소)
  • Published : 1989.02.20

Abstract

The fluorescence of $Eu^{3+},\;Tb^{3+}$ substituted for $La^{3+}$ in Lanthanum Oxychloride (LaOCl) has been studied. The fluorescence intensity of the $Eu^{3+},\;Tb^{3+}$ in LaOCl excited by Ultra-violet light were investigated on its activator concentration and discussed as the energy transfer process. The energy transfer from $Tb^{3+}\;to\;Eu^{3+}$ take place in the $Eu^{3+}\;and\;Tb^{3+}$ codoped LaOCl crystal. This process was confirmed to the change of concentration and the measurement of fluorescence decay time.

염화산화란탄(LaOCl) 결정속에서 La와 치환된 $Eu^{3+}$$Tb^{3+}$의 형광성질을 연구하였다. 자외선으로 들뜬 LaOCl의 형광세기를 활성제인 $Eu^{3+}$$Tb^{3+}$의 농도에 따라 고찰하였고, 이 현상을 활성제들 사이의 에너지 전달 과정으로 설명하였다. LaOCl 결정속에 $Eu^{3+}$$Tb^{3+}$를 같이 분포시키면 흡수된 에너지가 $Tb^{3+}$에서$Eu^{3+}$로 전달됨을 보았다. 치환된 활성제의 양에 따른 형광세기의 변화와 쇄잔시간의 측정으로부터 이 사실을 확인하였다.

Keywords

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