Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Bonding and Electronic Consideration in the Metal-Metal Bonded Edge Sharing Complexes

  • Jaejung Ko (Department of Chemical Education, Korea National University of Education) ;
  • Kuk-Tae Park (Department of Chemical Education, Korea National University of Education) ;
  • Ikchoon Lee (Department of Chemistry, Inha University) ;
  • LEe Bon-Su (Department of Chemistry, Inha University)
  • Published : 1989.12.20
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Abstract

The molecular interaction of $W_2(NH_2)_4Cl_4$ fragment with chlorine ligands has been studied by means of extended Huckel calculations. We have extended the Huckel calculation to unknown edge-sharing $W_2(NH_2)_4Cl_4({\eta}-X)_2$ complexes (X = CO, H) in order to compare the stability of the complexes. The calculations showed that the size and electronic property of bridged ligand are important in determining the stability. The stabilities of the related metal-metal bonded edge-sharing complexes are discussed.

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