Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Use of the Thermodynamic Solution Properties of Xenon in n-Alkanes for the Examination of Models for the Cavity Formation Process

  • Park, Jung-Hag (Department of Chemistry, Yeungnam University) ;
  • Brady, James E. (Department of Chemistry, University of Pittsburg) ;
  • Carr, Peter W. (Department of Chemistry, University of Minnesota)
  • Published : 1989.06.20
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Abstract

The interaction energies of Xenon in n-alkanes were estimated by using three models for the cavity formation process, Hildebrand's regular solution theory, Pierotti's scaled particle theory and Sinanoglu-Reiss-Moura-Ramos' solvophobic theory in an attempt to examine the validity of three models. It appears that Pierotti's implementation of scaled particle theory yields a reasonable estimate of cavity formation energy over a considerable range in solvent size provided that the solute is spherical enough as are the inert gases.

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