Bulletin of the Korean Chemical Society

  • 제10권3호
  • /
  • Pages.309-314
  • /
  • 1989
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Use of the Thermodynamic Solution Properties of Xenon in n-Alkanes for the Examination of Models for the Cavity Formation Process

  • Park, Jung-Hag (Department of Chemistry, Yeungnam University) ;
  • Brady, James E. (Department of Chemistry, University of Pittsburg) ;
  • Carr, Peter W. (Department of Chemistry, University of Minnesota)
  • 발행 : 1989.06.20
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초록

The interaction energies of Xenon in n-alkanes were estimated by using three models for the cavity formation process, Hildebrand's regular solution theory, Pierotti's scaled particle theory and Sinanoglu-Reiss-Moura-Ramos' solvophobic theory in an attempt to examine the validity of three models. It appears that Pierotti's implementation of scaled particle theory yields a reasonable estimate of cavity formation energy over a considerable range in solvent size provided that the solute is spherical enough as are the inert gases.

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참고문헌

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