Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Kinetic Energy Release in the Fragmentation of tert-Butylbenzene Molecular Ions. A Mass-analyzed Ion Kinetic Energy Spectrometric (MIKES) Study

  • Choe, Joong-Chul (Department of Chemistry, College of Natural Sciences, Seoul National University) ;
  • Kim, Byung-Joo (Department of Chemistry, College of Natural Sciences, Seoul National University) ;
  • Kim, Myung-Soo (Department of Chemistry, College of Natural Sciences, Seoul National University)
  • Published : 1989.04.20
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Abstract

Kinetic energy release in the fragmentation of tert-butylbenzene molecular ion was investigated using mass-analyzed ion kinetic energy spectrometry. Method to estimate kinetic energy release distribution (KERD) from experimental peak shape has been explained. Experimental KERD was in good agreement with the calculated result using phase space theory. Effect of dynamical constraint was found to be important.

Keywords

References

  1. Mass Spectronmetry M. S. Kim
  2. Fundamental Aspects of Organic Mass Spectrometry K. Levsen
  3. Metastable Ions R. G. Cooks;J. H. Beynon;R. M. Caprioli;G. R. Lester
  4. J. Am. Chem. Soc. v.110 M. A. Hanratty;J. L. Beauchamp;A. J. Illies;P. van Koppen;M. T. Bowers
  5. J. Phys. Chem. v.89 Y. Malinovich;R. Arakawa;G. Haase;C. Lifshitz
  6. J. Am. Chem. Soc. v.78 M. S. Kim;F. W. McLafferty
  7. Int. J. Mass Spectrom. Ion. Processes v.65 M. Rabrenovic;J. H. Beynon;S. H. Lee;M. S. Kim
  8. Int. J. Mass Spectrom. Ion. Phys. v.51 W. A. Brand;K. Levsen
  9. J. Am. Chem. Soc. v.100 M. S. Kim;R. C. Dunbar;F. W. McLafferty
  10. J. Chem. Phys. v.84 H. S. Kim;M. F. Jarrold;M. T. Bowers
  11. Int. J. Mass Spectrom. Ion Phys. v.49 W. A. Brand;T. Baer
  12. Bull. Korean Chem. Soc. v.10 Y. J. Kim;J. C. Choe;M. S. Kim
  13. Tandem Mass Spectrometry F. W. McLafferty(ed.)
  14. Pro. Nat. Acad. Sci. U.S. v.38 H. M. Rosenstock;M. B. Wallenstein;A. L. Wahrhaftig;H. Eyring
  15. Unimolecular Reactions P. J. Robinson;K. A. Holbrook
  16. J. Chem. Phys. v.40 J. C. Light
  17. J. Chem. Phys. v.42 P. Pechukas;J. C. Light
  18. J. Chem. Phys. v.43 J. C. Light;J. Lin
  19. Discuss. Faraday Soc. v.44 J. C. Light
  20. Theor. Exp. Chem. (USSR) v.1 E. Nikitin
  21. J. Phys. Chem. v.75 C. E. Klots
  22. Z. Naturforsch. v.27A C. E. Klots
  23. J. Chem. Phys. v.58 C. E. Klots
  24. J. Chem. Phys. v.64 C. E. Klots
  25. J. Am. Chem. Soc. v.98 W. J. Chesnavich;M. T. Bowers
  26. J. Am. Chem. Soc. v.99 W. J. Chesnavich;M. T. Bowers
  27. Chem. Phys. v.63 K. Johnson;I. Powis;C. J. Danby
  28. Ph. D. Thesis, University of California W. J. Chesnavich
  29. Prog. React. Kinet. v.11 W. J. Chesnavich;M. T. Bowers
  30. J. Phys. Chem. v.87 D. A. Webb;W. J. Chesnavich
  31. QCPE Bull. v.8 W. J. Chesnavich;L. Bass;M. E. Grice;K. Song;D. A. Webb
  32. Int. J. Mass Spectrom. Ion Phys. v.8 J. H. Beynon;A. E. Fontaine;G. R. Lester
  33. Proc. R. Soc. London v.A373 J. E. Szulejko;A. Mendez Amaya;R. P. Morgan;A. G. Brenton;J. H. Beynon
  34. Int. J. Mass Spectrom. Ion Phys. v.23 J. L. Holmes;A. D. Osborne
  35. Proc. R. Soc. London v.A373 A. Mendez Amya;A. G. Brenton;J. E. Szulejko;J. H. Beynon
  36. Int. J. Mass Spectrom. Ion Processes v.58 M. F. Jarrold;W. Wagner-Redeker;A.J . Illies;N. J. Kirchner;M. T. Bowers
  37. Int. J. Mass Spectrom. Ion Processes v.82 B. A. Rumpf;P. J. Derrick
  38. M. S. Kim
  39. Anal. Chem. v.36 A. Savitzky;M. J. E. Golay
  40. Discuss. Faraday Soc. v.55 R. A. Marcus
  41. Assignments for Vibrational Spectra of Seven Hundered Benzene Derivatives v.1 G. Varsanyi
  42. Int. J. Mass. Spectrom. Ion Processes v.58 P. C. Burgers;J. L. Holmes

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