Bulletin of the Korean Chemical Society

  • 제10권2호
  • /
  • Pages.134-137
  • /
  • 1989
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지
DOI QR코드

DOI QR Code

Kinetic Studies of Reactions of Transition Metal Carbonyl Anion with Allyl Halides

  • 발행 : 1989.04.20
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

The reaction of $CpMo(CO)_3-M^+(M^+,\;Li^+,\;Na^+,\;K^+,\;PPN^{+a})$ with allyl halide was performed and the details of its counterion effects and solvent effect was investigated under the pseudo-first order conditions. The kinetic data from this reaction were compared with those from the reaction of the same anion with benzyl halides in terms of their inverse counterion effects.

키워드

참고문헌

  1. J. Am. Chem. Soc. v.88 Dessy, R. E.;Pohl, R. L.;King, R.B.
  2. Acc. Chem. Res. v.8 Collman, J. P.
  3. J. Am. Chem. Soc. v.98 Darensbourg, M. Y.;Darensbourg, D. J.;Drew, D. A.;Burns, D.
  4. J. Organomet. Chem. v.212 Moro, A.;Foa, M.;Cassar, L.
  5. J. Am. Chem. Soc. v.104 Darensbourg, M. Y.;Jimenez, P.;Sackett, J. R.;Hankel, J. M.;Kump, R. L.
  6. J. Organomet. Chem. v.202 Darensbourg, M. Y.;Jimenez, P.;Sackett, J. R.
  7. J. Am. Chem. Soc. v.101 Watson, P. L.;Berman, R. G.
  8. Prog. Inorg. Chem. v.33 Darensbourg, M. Y.
  9. The Chemist's Companion Gordon, A. J.;Ford, R. A.
  10. Organomet. Synth. v.1 King, R. B.
  11. Inorg. Synth. v.7 King, R. B.;Stone, F. G. A.
  12. J. Am. Chem. Soc. v.98 Pannel, K. H.;Jackson, D. J.
  13. Inorg. Chem. v.20 Plotkin, J. S.;Shore, S. G.
  14. Prog. Inorg. Chem. v.33 Darensbourg, M. Y.
  15. J. Organomet. Chem. v.157 Birdwhistell, R.;Hackett, P.;Manning, A. R.
  16. Master thesis, Tulane University Sackett, J. R.
  17. J. Am. Chem. Soc. v.103 Darensbourg, M. Y.;Slater, S.
  18. Inorg. Chem. v.20 Darensbourg, M. Y.;Deaton, J. C.
  19. J. Am. Chem. Soc. v.100 Miller, A. R.
  20. Machanism and Theory in Organic Chemistry Lowry, T. H.;Richardson, K. S.