Journal of the Korean Society of Clothing and Textiles (한국의류학회지)

The Korean Society of Clothing and Textiles (한국의류학회)
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The Adsorption Mechanism of Copper (II) Ion on Acrylic Fiber Treated with Hydroxylamine

하이드록실 아민으로 처리한 아크릴섬유의 구리 (II)이온의 흡착기구

  • Chin Young-gil (Dept. of Clothing and Textiles, College of Natural Science. Gyeong Sang National University) ;
  • Choi Suk-chul (Dept. of Clothing and Textiles. College of Home Economics, Pusan National University)
  • 진영길 (경상대학교 자연과학대학 의류학과) ;
  • 최석철 (부산대학교 가정대학 의류학과)
  • Published : 1988.04.01
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Abstract

In order to investigate a practical application of the fibrous adsorbent to heavy metal ions, acrylic fibers were treated with the hydroxylamine solution that was producted by hydroxylamine hydrochloride and potasium hydroxide in a condition of strong alkaline and $70^{\circ}C$. The adsorption mechanism of copper(2) ion on the fibrous adsorbent, that is hydroxylaminated acrylic fibers, was studied. The adsorption of copper(2) ion was explained in terms of the activated adsorption that are formed the complex with the ligand, such as C=N, N-H, NHOH, on the surface of the adsorbent. The activation energy was evaluated to be 3.8 Kcal/mol. and the times of adsorption equilibrium was approximately 10 minutes. The uptake of copper(2) ion was found to be effected with the increase of temperatures and the pH dependence.

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