Separation of Inorganic Anions by Reversed-phase Ion Chromatography

역상 이온 크로마토그래피에서 무기음이온의 분리

  • Kih Soo Joe (Korea Advanced Energy Research Institute Chungnam) ;
  • Tae Yoon Eom (Korea Advanced Energy Research Institute Chungnam) ;
  • Seung Soo Kim (Korea Advanced Energy Research Institute Chungnam) ;
  • Youn Doo Kim (Department of Chemistry, Chungnam National University)
  • Published : 1988.10.20

Abstract

Capacity factors (k') of some inorganic anions including $BF_4^{-1}$ were measured on cetylpyridinium coated column, and with dynamic system using tetrabutylammonium salicylate on PRP-1 reversed-phase column, respectively. After optimum separation condition was obtained this method was applied to the determination of boron in some different type samples.

PRP-1 역상 충전제에 Cetylpyridinium Chloride를 흡착한 흡착분리관과 Tetrabutylammonium을 이온상호작용제로 사용하는 동적계에서 $BF_4^{-1}$를 포함하는 무기음이온들의 크기인자(k')를 측정하였다. 용리액의 농도, pH변화에 따라 이들 이온들의 분리조건을 검토한 후 폐기물 시료중 붕소정량에 적용하였다

Keywords

References

  1. Anal. Chem. v.54 Z. Iskandarani;D.J. Pietrzyk
  2. J. Chromatogr. Sci. v.21 R.M. Cassidy;S. Elchuk
  3. J. Chromatography v.262 R.M. Cassidy;S. Elchuk
  4. Anal. Chem. v.54 Z. Iskandarani;D.J. Pietrzyk
  5. J. Chromatography v.177 Roger Neil Reeve
  6. J. Chromatography v.314 Jan Andrasko
  7. Analyst v.109 Frank G. P.;Mullins;Gordon F. Kirkbright
  8. J. Chromatography v.300 P.R. Haddad;A.L. Heckenberg
  9. Anal. Chem. v.52 C.S. Hill;R.P. Lash
  10. Anal. Chem. v.52 J. Gulens;Paul K. Leeson
  11. Anal. Chem. v.56 Purnendu K.;Dasgupta
  12. Anal. Chem. v.54 Z. Iskandarani;D.J. Pietrzyk