Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Surface Enhanced Raman Scattering of Methoxybenzonitriles in Silver Sol

  • Boo, Doo-Wan (Department of Chemistry, Seoul National University) ;
  • Kim, Myung-Soo (Department of Chemistry, Seoul National University) ;
  • Kim, Kwan (Department of Chemistry, Seoul National University)
  • Published : 1988.10.20
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Abstract

The surface-enhanced Raman scattering(SERS) of methoxybenzonitrile in a silver sol was investigated. All of ortho-, meta-, and para-substituted benzonitriles were found to adsorb on the silver surface via the nitrogen lone pair electrons. The benzene ring of meta derivative seemed likely to stand perpendicular to the silver surface, while the benzene rings of both otho and para derivatives assumed tilted stances with respect to the surface. The SERS technique appeared to be a useful means to study the substituent electronic effects.

Keywords

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