Bulletin of the Korean Chemical Society

  • 제9권5호
  • /
  • Pages.311-317
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  • 1988
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Surface Enhanced Raman Scattering of Methoxybenzonitriles in Silver Sol

  • Boo, Doo-Wan (Department of Chemistry, Seoul National University) ;
  • Kim, Myung-Soo (Department of Chemistry, Seoul National University) ;
  • Kim, Kwan (Department of Chemistry, Seoul National University)
  • 발행 : 1988.10.20
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초록

The surface-enhanced Raman scattering(SERS) of methoxybenzonitrile in a silver sol was investigated. All of ortho-, meta-, and para-substituted benzonitriles were found to adsorb on the silver surface via the nitrogen lone pair electrons. The benzene ring of meta derivative seemed likely to stand perpendicular to the silver surface, while the benzene rings of both otho and para derivatives assumed tilted stances with respect to the surface. The SERS technique appeared to be a useful means to study the substituent electronic effects.

키워드

참고문헌

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피인용 문헌

  1. ChemInform Abstract: Surface‐Enhanced Raman Scattering of Methoxybenzonitriles in Silver Sol. vol.20, pp.16, 1988, https://doi.org/10.1002/chin.198916039
  2. Surface-enhanced Raman spectroscopic study of hydrocinnamonitrile adsorbed on silver surface vol.213, pp.None, 1988, https://doi.org/10.1016/0022-2860(89)85106-3
  3. Surface-enhanced Raman scattering of 4-methoxybenzylcyanide in silver sol vol.216, pp.None, 1990, https://doi.org/10.1016/0022-2860(90)80315-b
  4. Adsorption and reaction of trans-cinnamonitrile of a silver surface investigated by raman spectroscopy vol.221, pp.None, 1988, https://doi.org/10.1016/0022-2860(90)80396-2
  5. Investigation of adsorption and decomposition of 4‐(methylthio)benzonitrile on a silver surface by Raman spectroscopy vol.24, pp.4, 1988, https://doi.org/10.1002/jrs.1250240406
  6. Adsorption of aromatic nitriles on silver investigated by Raman spectroscopy vol.298, pp.None, 1988, https://doi.org/10.1016/0022-2860(93)80206-b
  7. Theoretical surface-enhanced Raman spectra study of substituted benzenes : I. Density functional theoretical SERS modelling of benzene and benzonitrile vol.71, pp.3, 1988, https://doi.org/10.1016/j.saa.2008.02.046
  8. Theoretical surface-enhanced Raman spectra study of substituted benzenes : II. Density functional theoretical SERS modelling of o-, m-, and p-methoxybenzonitrile vol.71, pp.3, 2008, https://doi.org/10.1016/j.saa.2008.03.007
  9. 금속콜로이드 표면에 흡착된 4-Biphenyl Acetonitrile의 흡착배향 유도에 관한 형광 연구 vol.53, pp.4, 2009, https://doi.org/10.5012/jkcs.2009.53.4.399