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Raman Spectroscopy of L-Phenylalanine, L-Tyrosine, and their Peptides Adsorbed on Silver Surface

  • Lee, Hong-In (Department of Chemistry, College of Natural Sciences, Seoul National University) ;
  • Kim, Myung-Soo (Department of Chemistry, College of Natural Sciences, Seoul National University) ;
  • Suh, Se-Won (Department of Chemistry, College of Natural Sciences, Seoul National University)
  • Published : 1988.08.20

Abstract

The surface-enhanced Raman scattering of L-phenylalanyl-glycine (L-Phe-Gly), L-phenylalanyl-glycyl-glycine (L-Phe-Gly-Gly), glycyl-glycyl-L-phenylalanine (Gly-Gly-L-Phe), L-tyrosyl-glycine (L-Tyr-Gly), and L-tyrosyl-glycyl-glycine (L-Tyr-Gly-Gly) adsorbed on silver colloidal particles have been investigated. More detailed investigations on the surface-enhanced Raman scattering from L-phenylalanine (L-Phe), glycyl-L-phenylalanine (Gly-L-Phe), L-tyrosine (L-Tyr), and glycyl-L-tyrosine (Gly-L-Tyr) than in ref. 17 have also been made. It has been found that the above molecules adsorb on the surface via both the carboxylate ($COO^-$) and amino ($NH_2$) groups.

Keywords

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