Bulletin of the Korean Chemical Society

  • 제9권3호
  • /
  • Pages.161-164
  • /
  • 1988
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  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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A Gas Phaes Kinetic Study of the Energy Transfer by using the High Power CO$_2$ Laser. (II). Decomposition of $BrCH_2CH_2CH_2CH_2Cl$

  • 발행 : 1988.06.20
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초록

Infrared multiphoton decompositions (IRMPD) of $BrCH_2CH_2CH_2CH_2Cl$ were studied by using the pulsed $CO_2$laser. At 0.3 J laser energy the experimentally observed product ratios could be reasonably explained by the RRKM calculation with initial excitation energy of ca. 80 Kcal/mol. The pressure dependence of product yields led us to conclude that the collisional deactivation by the inert gas decreased the yield of low energy dissociation channel more significantly.

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참고문헌

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