Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Mechanism for Chemiluminescent Reactions of Bis(2,4,6-trichlorophenyl)oxalate, Hydrogen Peroxide and Fluorescent Aromatic Hydrocarbons

  • Published : 1988.02.20
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Abstract

A mechanistic study on the chemiluminescence resulting from the reaction between bis(2,4,6-trichlorophenyl)oxalate(TCPO) and hydrogen peroxide in the presence of fluorescent polycyclic aromatic hydrocarbons in a viscous phthalate medium has been conducted. The rate determining step, decay rate constants, and relative quantum efficiencies yielded by varying the concentration of reagents generally support an existing mechanism. However, a reaction between TCPO and sodium salicylate was not observed.

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References

  1. J. Am. Chem. Soc. v.89 M. M. Rauhut(et al.)
  2. Analyst v.108 L. J. Kricka;G. H. G. Thorpe
  3. Anal. Chem. v.55 K. Honda;J. Sekino;K. Imai
  4. Anal. Chem. v.56 K. W. Sigvardson;J. M. Kennish;J. W. Birks
  5. Anal. Chem. v.55 K. W. Sigvardson;J. W. Birks
  6. Korea Patent S. B. Tae;Y. I. Hwang
  7. Prog. Org. Chem. v.8 F. McCapra
  8. J. Chem. Soc., Faraday Trans. 2 v.80 C. L. R. Catherall;T. F. Palmer;R. B. Cundall
  9. J. Am. Chem. Soc. v.108 F. J. Alvarez(et al.)
  10. Chemi-and Bioluminescence A. G. Mohan;J. G. Burr(ed.)
  11. J. Chem. Educ. v.51 A. G. Mohan;N. J. Turro

Cited by

  1. ChemInform Abstract: Mechanism for Chemiluminescent Reactions of Bis(2,4,6‐trichlorophenyl)oxalate, Hydrogen Peroxide and Fluorescent Aromatic Hydrocarbons. vol.19, pp.35, 1988, https://doi.org/10.1002/chin.198835096