Bulletin of the Korean Chemical Society

  • 제9권1호
  • /
  • Pages.10-12
  • /
  • 1988
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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The Nature of the Intrinsic Barrier in Methyl Transfer Reactions

  • 이익준 (인하대학교 이과대학 화학과) ;
  • 송창현 (인하대학교 이과대학 화학과)
  • 발행 : 1988.02.20
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초록

The intrinsic barrier in the methyl transfer reaction $X^- + CH_3X \rightleftharpoons XCH_3 + X^-$ has been shown to vary quadratically with the C-X distance d; linear dependence of the intrinsic barrier on the deformation energies or methyl cation affinities of the substrate, $CH_3X$, should therefore hold only approximately in a narrow range of structural variations in X.

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참고문헌

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