한국세라믹학회지 (Journal of the Korean Ceramic Society)

  • 제25권6호
  • /
  • Pages.571-576
  • /
  • 1988
  • /
  • 1229-7801(pISSN)
  • /
  • 2234-0491(eISSN)
한국세라믹학회 (The Korean Ceramic Society)
권호 표지

Pb[Cd1/2W1/2)0.02Zr0.505Ti0.475]O3조성에서의 MnO2첨가에 대한 영향

Effect of MnO2 Addition on Electrical Properties and Microstructure in Pb[Cd1/2W1/2)0.02Zr0.505Ti0.475]O3

  • 김대웅 (한국과학기술원 재료공학과) ;
  • 김병익 (한국과학기술원 재료공학과) ;
  • 김호기 (한국과학기술원 재료공학과)
  • 발행 : 1988.06.01
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

The microstructure and electrical properties of 0.02Pb[Cd1/2W1/2)O3-0.505PbZrO3-0.475PbTiO3 with MnO2 addition have been investigated. The amount of MnO2 addition was 0, 0.2, 0.4, 0.6, 0.8, 1wt%, respectively. When MnO2 is added up to 0.2wt%, Mn3+ which is substituted for Ti4+ site make hole and act as a acceptor. When MnO2 is added over 0.2wt% Mn3+ which is substituted for Cd2+ site create electron and act as a donor. The variation of grain size show that it was rapidly increased by 0.4wt% addition of MnO2, and while that in the range of over 0.6wt% addition of MnO2 it was decreased. The solid solution range of MnO2 that assumed in this composition according to the variations of microstructure and electrical properties was 0.4-0.6wt%.

키워드

참고문헌

  1. Jap. Appl. Phys. v.10 no.5 Electrical Resistivity of Lead Zirconate Titanate Ceramic Containing Impurities M. Takashi
  2. Sov. Phys. Solid State. v.10 no.4 Properties of Pb(Ti, Zr)O₃Piezoelectric Ceramic and Nature of Their Orientational Dielectric Polarzation V.A. Isupov
  3. Jap. J. Appl. Phys. v.11 no.1 Effects of Impurities on the Mechanical Quality Factor of Lead Ziroconate Titanate Ceramics S. Takahashi;M. Takahashi
  4. Jap. J. Appl. Phys. v.11 no.1 Piezoelectric Properties of Pb(Mg⅓Nb⅔)O-PbTiO₃-PbZrO₃Ceramics Modified with Certain Additivies H. Ouchi;M. Nishida;S. Hayakawa
  5. J. Canadian.Ceram. Soc. v.50 no.23-28 Poling of Piezoelectric Ceramics M. Sayer;B.A. Judd;K. El-Assal;E. Prasad
  6. Ferro v.76 no.327-333 Characteristics of Domain in Tetragonal Phase PZT Ceramics H.T. Chung;H.G. Kim
  7. J. Am. Ceram. Soc. v.49 no.1 Phenominological Theory of High Permittivity in Fine-Grained Barium Titanate W.R.Buessem;L.E.Cross;A.K.Goswami
  8. Acta. Met. v.5 no.11 A Quantitative Theory of Grain-Boundary Motion and Recrystallization in Matels in the Persence of Impurities K.Lucke;K.Deterk
  9. J. Am. Ceram. Soc. v.54 no.5 Point Defects and Sintering of Lead Zirconate Titanate R.B.Atkin;Richard M.Fulrath
  10. J. Appl. Phys. v.49 no.8 Dielectric Losses in Ferroelectric Cermics Produced by Domain-Wall Mobility J.O.Genter;P.Gerthsen;N.A.Schmidt;R.E.Send
  11. Ferro v.51 Structural Studies of Manganes Stabilized Lead Zirconate Titanate Y.S.Ng;S.M.Alexander
  12. 박사학위논문 Pb(Zr, Ti)O₃-Pb(Mg, Nb)O₃에 MnO₂첨가 영향에 대한 효과 박창엽;김현재