한국세라믹학회지 (Journal of the Korean Ceramic Society)

  • 제25권3호
  • /
  • Pages.261-267
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  • 1988
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  • 1229-7801(pISSN)
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  • 2234-0491(eISSN)
한국세라믹학회 (The Korean Ceramic Society)
권호 표지

완도납석으로부터 제조한 $\beta$-Sialon에 대한 SiC의 복합화 효과

Effect of SiC Dispersion of $\beta$-Sialon Prepared from Wando Pyrophylite

  • 이홍림 (연세대학교 요업공학과) ;
  • 김신 (연세대학교 요업공학과) ;
  • 이형직 (현대자동차주식회사 연구소)
  • 발행 : 1988.03.01
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초록

완도납석과 carbon black 의 혼합물을 135$0^{\circ}C$에서 질소분위기를 사용하여 탄소환원질화법으로 $\beta$-Sialon 분물에 $\beta$-SiC를 제2상으로 넣어서 $Y_2O_3$와 $ZrO_2$를 각 소결조제로 사용하여 175$0^{\circ}C$에서 2시간 동안 상압소결하였다. 10wt %의 $Y_2O_3$를 소결조제로 사용하였을 때에 파괴인성은 3.8MN/m^{3/2}$, 3점꺽임 강도는 470MN/$m^2$ 그리고 경도는 13.7MN/$m^2$로서 좋은 값을 나타내었다. 이와 같은 파괴인성과 꺽임강도의 증가는 균열편향과 균열나눠짐에 의한 것으로 생각된다.

$\beta$-Sialon powder was prepared by the reduction-nitridation reaction from the mixture of Wando Pyrophyllite and carbon black at 135$0^{\circ}C$ in $N_2$ atmosphere. $\beta$-SiC powder was added to the prepared $\beta$-Sialon powder to make $\beta$-Sialon-SiC composite. The $\beta$-Sialon-SiC composites were sintered pressurelessly at 175$0^{\circ}C$ for 2h, using $Y_2O_3$ and $ZrO_2$(monoclinic) as sintering aids. Comparatively higher values of the fracture toughness (3.8 MN/㎥/2), M.O.R. (470 MN/$m^2$) and vickers microhardness (13.7 MN/$m^2$) were obtained when 10 wt% $Y_2O_3$ was added as a sintering aid. The improved fracture toughness and M.O.R. are assumed to be the results of crack deflection and crack branching by the second phase SiC particles.

키워드

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