FT-IR 및 Raman 분광법에 의한 $Na_2O$-$Ga_2O_3$-$SiO_2$ 계 유리의 구조분석

Structural Analysis of $Na_2O$-$Ga_2O_3$-$SiO_2$ System Glasses by FT-IR and Raman Spectroscopy

  • 황진명 (인하대학교 공과대학 무기재료공학과) ;
  • 이전 (인하대학교 공과대학 무기재료공학과) ;
  • 배인국 (인하대학교 공과대학 무기재료공학과)
  • Whang, Chin-Myung (Dept. of Ceramic Engineering, Collge of Engineering, Inha University) ;
  • Rhee, Jhun (Dept. of Ceramic Engineering, Collge of Engineering, Inha University) ;
  • Bae, In-Kook (Dept. of Ceramic Engineering, Collge of Engineering, Inha University)
  • 발행 : 1988.01.01

초록

In order to investigate the reason of changes in the physical properties of glasses near the region for which R(Ga/Na)=1, spectroscopic studies using FT-IR and Raman spectroscopy have been carried out on Na2O.2SiO2 glass with addition of Ga2O3 from 0 to 35 mole %, i.e., from R=0 to 1.61. The main purpose of this work is to investigate the coordination number of Ga3+ in glass with variation of glass composition and to determine the existence of tricluster in the Ga-rich region for which R>1.0 in Na2O-Ga2O3-SiO2 system.

키워드

참고문헌

  1. J. Am. Ceram. Soc. v.45 no.10 Properties of Soda Aluminosilicate Glasses: 1, Refractive Index, Density, Molar Refractivity, and Infrared Absorption Spectra D.E. Day;G.E. Rindone
  2. J. Chem. Phys. v.44 no.8 Structure of Sodium Aluminosilicate Melt Containing at Least 50mol% SiO₂at 1500℃ E.F. Riebling
  3. Phys. Chem. Glasses v.4 no.6 Aluminium in Glasses and in Melts E.D. Lacy
  4. Yogyo-Kyokai-Shi v.78 no.12 Study on the X-ray Radial Distribution Function of High Alumina Glass T. Moori;H. Morikawa;S. Iwai;H. Tagai
  5. J. Japan Inst. Metals. v.45 no.9 On the Infrared Emission Spectra of the Molten $Na_2O-Al_3O_3SiO_2$System K. Kusabiraki;Y. Shiraishi
  6. J. Non-Cryst. Solids v.68 Raman Studies of Al Coordination in Silica-Rich Sodium Aluminosilicate Glasses and Some Related Minerals M.A. Mckeown;F.L. Galeener;G.E. Brown
  7. J. Chem. Soc. Japan v.10 Some Physical Properties and State Analysis of Glasses in the System of $Na_2O-Ga_2O_3-SiO_2$ T. Hanada;S. Goto;R. Ota;N. Soga
  8. J. Non-Cryst. Solids v.45 Helium Migration in Alkali Galliosilicate Glasses J. E. Shelby
  9. Yogyo-Kyokai-Shi v.93 no.11 Raman Study of Glasses in the System $CaO-Ga_2O_3-B_2O_3$ X-J. Zhao;J. Fukunage;N. Yoshida;M. Ihara
  10. J. Appl. Phys. v.43 no.11 Infrared Absorption Spectra of Sodium Silicate Glass at High Pressures J.R. Ferraro
  11. J. Non-Cryst. Solids v.66 Glass Formation and Properties in the Gallia-Calcia System G. Whichard;D.E. Day
  12. J. Non-Cryst. Solids v.23 Raman Spectroscopic Investigation of the Structure of Silicate Glasses, II. Soda-Alkaline Earth-Alumina Ternary and Quarternery Glasses S.A. Brawer;W.B. White
  13. Am. Mineral. v.66 The Structural Role of Aluminum in Silicate Melts - A Raman Spectroscopic Study at 1 Atmosphere B.O. Mysen;D. Virgo;I. Kushiro
  14. Yogyo-Kyokai-Shi v.92 no.4 Structural Investigation of $$Rb_2O\cdot4SiO_2$$Glass and Melt by Raman Spectroscopy N. Iwamoto;N. Umesaki;K. Dohi
  15. J. Non-Cryst. Solids v.84 Raman Spectra of Alkali Galliosilicate Glasses of the Series $$20R_2O-XGa_2O_3-(80-X)\;SiO_2$ P.L. Higby;J.E. Shelby;R.A. Condrate
  16. J. Non-Cryst. Solids v.45 Structural Analysis of $Na_O-Ga_2O_3-SiO_2$Glasses by the X-Ray Diffraction Method N. Iwamoto;N. Umesaki;S. Goto;T. Hanada;N. Soga
  17. The Crystalline State v.4 Crystal Structure of Mineral S.L. Bragg;G.F. Claringbull;W.H. Taylor;L.Bragg(ed)
  18. Phys. Chem. Glasses v.28 Infrared Spectra of Alkali Galliosilicate and Aluminosilicate Glass P.L. Higby;J.E. Shelby;R.A. Condrate, Snt
  19. Spectrochim. Acta v.38A Etude Vibrationnelle d'aluminates et de Gallates de Terres rares - IIII. Aluminates et Gallates de Structure Grenat M.C. Saine;E. Husson et;H. Brusset
  20. Spectrochim. Acta v.26A Interpretation des spectres de Raman de Verres de Silice binaires J. Etchepare
  21. J. Non-Cryst. Solids v.69 Raman Spectra Structure of Sodium Aluminogermanate Glasses Shiv K. Sharma;Dean W. Matson