대한화학회지 (Journal of the Korean Chemical Society)

  • 제31권4호
  • /
  • Pages.359-363
  • /
  • 1987
  • /
  • 1017-2548(pISSN)
  • /
  • 2234-8530(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지

유기초음파화학·초음파가 $BaMnO_4$ 및 $KMnO_4-CuSO_4{\cdot}5H_2O$를 이용한 알코올의 산화반응에 미치는 영향

The Effects of Sonic Waves on the Oxidation Reaction of Alcohols Using $BaMnO_4\;and\;KMnO_4-CuSO_4{\cdot}5H_2O$

  • 유의상 (충남대학교 자연과학대학 화학과) ;
  • 신대현 (충남대학교 자연과학대학 화학과) ;
  • 한병희 (충남대학교 자연과학대학 화학과)
  • Eui Sang Ryoo (The Department of Chemistry, College of Natural Science, Chungnam National University) ;
  • Dae Hyun Shin (The Department of Chemistry, College of Natural Science, Chungnam National University) ;
  • Byung Hee Han (The Department of Chemistry, College of Natural Science, Chungnam National University)
  • 발행 : 1987.08.20
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초록

초음파(50KHz)가 상온 상압하에서 $BaMnO_4$ 및 $KMnO_4-CuSO_4{\cdot}5H_2O$를 이용한 1차, 벤질, 2차 알코올의 알데히드 및 케톤 생성반응을 가속 완결시켰으며 고속교반이나 가열 환류반응보다 높은 산화율을 주었다.

Sonic waves (50KHz) was accelerated the oxidation reaction of primary, benzyl and secondary alcohol with $BaMnO_4\;and\;KMnO_4-CuSO_4{\cdot}5H_2O$ to give the corresponding aldehyde and ketone at $30^{\circ}C/1$ atm. in high yields compared to stirring or refluxing condition.

키워드

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