Bulletin of the Korean Chemical Society

  • 제8권6호
  • /
  • Pages.466-470
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  • 1987
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  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Synthetic Applications of Di-2-pyridyl Thionocarbonate As a Dehydration, a Dehydrosulfuriation, and a Thiocarbonyl Transfer Reagent

  • Kim, Sung-Gak (Department of Chemistry, Korea Advanced Institute of Science and Technology) ;
  • Yi, Kyu-Yang (Department of Chemistry, Korea Advanced Institute of Science and Technology)
  • 발행 : 1987.12.20
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초록

Di-2-pyridyl thionocarbonate, prepared from thiophosgene and 2-hydroxypyridine in the presence of triethylamine in dichloromethane, was found to be very effective for dehydration, dehydrosulfurization, and thiocarbonyl transfer reactions. Di-2-pyridyl thionocarbonate was successfully for the esterification of carboxylic acids, dehydration of aldoximes into nitriles, preparation of isothiocyanates from amines, and preparation of cyclic thionocarbonates from 1,2- and 1,3-diols.

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참고문헌

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피인용 문헌

  1. Differentiating Antiproliferative and Chemopreventive Modes of Activity for Electron-Deficient Aryl Isothiocyanates against Human MCF-7 Cells vol.13, pp.16, 1987, https://doi.org/10.1002/cmdc.201800348