Bulletin of the Korean Chemical Society

  • 제8권6호
  • /
  • Pages.449-453
  • /
  • 1987
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Temperature Dependence of the Vibration-Vibration Energy Transfer in the Deexcitaion of NO(2) by NO(0)

  • Ree, Jong-Baik (Department of Chemistry Education, College fo Education, Chonnam National University) ;
  • Sohn, Chang-Kook (Department of Chemistry Education, College fo Education, Chonnam National University) ;
  • Lee, Chang-Soon (Department of Chemistry, Inha University) ;
  • Kim, Yoo-Hang (Department of Chemistry, Inha University)
  • 발행 : 1987.12.20
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초록

The temperature dependence of the vibrational relaxation of NO(= 2) by NO(v = 0) has been investigated over the temperature range 100-3000 K. We have assumed that the deexcitation of NO(2) by NO(0) undergoes vibration-to-vibration (VV) energy exchange with the transfer of the energy mismatch ${\Delta}$E through rotation (R) and translation(T). The relaxation rate constants are calculated by solving the time-dependent Schrodinger equation. The sum of V-V, T, and V-V, R contributions shows very weak temperature dependence and is in reasonable agreement with observed data over the temperature range 300-3000 K.

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참고문헌

  1. J. Chem. Phys. v.59 J. C. Stephenson
  2. J. Chem. Phys. v.60 J. C. Stephenson
  3. Chem. Phys. v.50 J. Kosanetzky;U. List;W. Urban;H. Vormann;E. H. Fink
  4. Chem. Phys. Letters v.91 M. R. da Silva;M. H. Vasconcelos;F. Lepoutre;M. Y. Perrin
  5. J. Chem. Phys. v.50 C. J. Hochanadal;J. A. Ghormley
  6. Japan. J. Appl. Phys. v.18 H. Horiguchi;S. Tsuchiya
  7. Chem. Phys. v.22 K. Glanzer
  8. Chem. Phys. v.94 R. G. Macdonald;F. C. Sopchyshyn
  9. Trans. Faraday Soc. v.67 J. Billingsley;A. B. Callear
  10. J. Chem. Phys. v.60 H. K. Shin
  11. J. Chem. Phys. v.63 H. K. Shin
  12. J. Chem. Phys. v.64 H. K. Shin;Y. H. Kim
  13. J. Chem. Phys. v.73 H. K. Shin;Y. H. Kim
  14. J. Chem. Phys. v.75 H. K. Shin
  15. J. Chem. Phys. v.78 H. K. Shin
  16. J. Chem. Phys. v.57 G. C. Berend;R. L. Thommarson;S. W. Benson
  17. J. Chem. Phys. v.57 G. D. B. Sorensen
  18. J. Chem. Phys. v.58 G. C. Berend;R. L. Thommarson
  19. Chem. Phys. v.50 G. D. Billing
  20. J. Chem. Phys. v.78 J. B. Ree;T. Ree;H. K. Shin
  21. Opt. Spectrosk. v.6 E. E. Nikitin
  22. Opt. Spectrosc. (USSR) v.6 E. E. Nikitin
  23. J. Phys. Chem. v.75 H. K. Shin
  24. Rotating Diatomic Molecules M. Mizushima
  25. Chemical Kinetics R. E. Weston Jr.;H. A. Schwarz
  26. Chem. Rev. v.69 D. Rapp;T. Kassal
  27. Chem. Phys. v.95 M. M. Maricq;E. A. Gregory;C. J. S. M. Simpson
  28. Chem. Phys. v.104 D. W. Lupo;H. Abdel-Halim;G. E. Ewing