Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Partial Reduction of Nitriles to Aldehydes by Thexylbromoborane-Methyl Sulfide$^\dag$

  • Cha, Jin-Soon (Department of Chemistry, College of Science, Yeungnam University) ;
  • Oh, Se-Yeon (Department of Chemistry, College of Science, Yeungnam University) ;
  • Kim, Jin-Euog (Department of Chemistry, College of Science, Yeungnam University)
  • Published : 1987.08.20
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Abstract

A systematic study of the partial reduction of nitriles to the corresponding aldehydes with thexylbromoborane-methyl sulfide $(ThxBHBr{\cdot}SMe_2)$ under practical conditions has been carried out. The yields of aldehydes are good in the aliphatic series. However, the yields of aromatic series vary with substituents and ring itself.

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References

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