Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Palladium Dichloro Complex Catalysed Oxidation of Cyclopentene by Dioxygen in Tetralin$^\dag$

  • Takehira, Katsuomi (National Chemical Laboratory for Industry, Tsukuba Research Center) ;
  • Hayakawa, Takashi (National Chemical Laboratory for Industry, Tsukuba Research Center) ;
  • Orita, Hideo (National Chemical Laboratory for Industry, Tsukuba Research Center) ;
  • Shimizu, Masao (National Chemical Laboratory for Industry, Tsukuba Research Center) ;
  • Oh, In-Hwan (Department of Chemistry, Sogang University)
  • Published : 1987.08.20
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Abstract

Palladium dichloro complexes catalysed the oxidation of cyclopentene by dioxygen in tetralin solvent at ambient temperature. Cyclopentanone formed mainly together with autoxidation products from both cyclopentene and tetralin. The oxidation seems to proceed by co-oxidation mechanism, where tetralin was first oxidized to its hydroperoxide which then oxidized cyclopentene to cyclopentanone. Mechanism of the other by-products formations has been discussed.

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References

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