Bulletin of the Korean Chemical Society

  • 제8권4호
  • /
  • Pages.254-257
  • /
  • 1987
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  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Palladium Dichloro Complex Catalysed Oxidation of Cyclopentene by Dioxygen in Tetralin$^\dag$

  • Takehira, Katsuomi (National Chemical Laboratory for Industry, Tsukuba Research Center) ;
  • Hayakawa, Takashi (National Chemical Laboratory for Industry, Tsukuba Research Center) ;
  • Orita, Hideo (National Chemical Laboratory for Industry, Tsukuba Research Center) ;
  • Shimizu, Masao (National Chemical Laboratory for Industry, Tsukuba Research Center) ;
  • Oh, In-Hwan (Department of Chemistry, Sogang University)
  • 발행 : 1987.08.20
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초록

Palladium dichloro complexes catalysed the oxidation of cyclopentene by dioxygen in tetralin solvent at ambient temperature. Cyclopentanone formed mainly together with autoxidation products from both cyclopentene and tetralin. The oxidation seems to proceed by co-oxidation mechanism, where tetralin was first oxidized to its hydroperoxide which then oxidized cyclopentene to cyclopentanone. Mechanism of the other by-products formations has been discussed.

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참고문헌

  1. The Chemistry of Functional Groups, Peroxide S. Patai
  2. J. Am. Chem. Soc. v.110 H. Mimoun;M. M. P. Machirant;I. Seree de Roch
  3. J. Am. Chem. Soc. v.102 H. Mimoun;R. Charpantier;A. Mitschler;J. Fischer;R. Weiss
  4. Chem. Lett. K. Takehira;T. Hayakawa;H. Orita
  5. K. Takehira
  6. Inorg. Chem. v.8 B.B. Wayland;R.F. Schramm
  7. J. Chem. Soc. T.A. Stephenson;S.M. Morehouse;A.R. Powell;J.P. Heffer;G. Wilkinson
  8. Ann. Chem. v.591 L. Horner;W. Jurgleit
  9. Organic Synthesis, Col. v.IV H.B. Knight;D. Swern

피인용 문헌

  1. Oxidation of bicyclic arenes with hydrogen peroxide catalysed by Mn(III) porphyrins vol.232, pp.1, 1987, https://doi.org/10.1016/j.molcata.2005.01.042