Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Raman Spectroscopic Study of Benzonitrile on Silver Surface

  • Boo, Doo-Wan (Department of Chemistry, College of Natural Sciences, Seoul National University) ;
  • Kim, Kwan (Department of Chemistry, College of Natural Sciences, Seoul National University) ;
  • Kim, Myung-Soo (Department of Chemistry, College of Natural Sciences, Seoul National University)
  • Published : 1987.08.20
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Abstract

The surface-enhanced Raman scattering(SERS) of benzonitrile in a silver sol was investigated. It was concluded that the molecule adsorbed onto the silver surface via the nitrogen lone pair electrons. Using the surface selection rule, the orientation of the benzene ring with respect to the surface plane could not be determined conclusively. However, it seemed likely that benzonitrile is adsorbed edge-on to the surface. It was demonstrated that the SERS technique provides a useful method for detailed characterization of the chemisorbed layer.

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References

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