Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Proton Magnetic Resonance Study of the Amino Group of Thioacetamide (TA) I. Quadrupole Relaxation Effects in NH$_2$ of Thioacetamide

  • Published : 1987.08.20
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Abstract

Nitrogen-14 quadrupolar relaxation has been observed in the amino proton nmr spectra of TA in acetone and methanol solutions over the temperature range $-83^{\circ}C\; to\;+35^{\circ}C.$ The proton nmr lineshapes were analyzed to yield a $^{14}N$ spin lattice relaxation time $(T_1)_N$ as a function of temperature. Activation energies and correlation times at $25^{\circ}C$ for the molecular reorientation in the two solution phases have been calculated and the results are discussed.

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References

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