Determination of Tire Tread Rubber in the Atmospheric Particulate Matters by Pyrolysis-Gas Chromatography

열분해 가스크로마토그래피에 의한 대기입자상 물질중의 타이어 트래트 고무성분의 정량

  • 李龍根 ;
  • 金萬九 ;
  • 金南勳 ;
  • 黃圭子
  • Published : 1987.11.01

Abstract

Rubber particles emitted from automobile tire tread by abrasion were collected by Andersen sampler with atmospheric dusts. The samples of atmospheric dusts at each stage were analysed for rubber particles by Curie point pyrolysis-gas chromatography with Apiezon grease L column. Pyrolysis was done at 740$^circ$C for 5 seconds. In the pyrogram, NR rubber (bus and truck tire tread) was determined by isoprene peak, and SBR rubber (passenger car tire tread) was determined by styrene peak simultaneously. The size distribution of rubber particles was proportioned with the size of rubber particles. The concentrations of NR and SBR rubber were 0.23 $\mug/m^3$ and 1.31 $\mug/m^3$, respectively, in the atmospheric dusts which were collected from the street in front of Yonsei University on April 1986. The ratio of tire tread rubber in the atmospheric dusts was about 0.63%.

Keywords

References

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