Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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Rates and Mechanism of Reduction of Vanadium(V) by Ethanol in Sulfuric Acid

황산용액에서 에탄올에 의한 바나듐(V) 의 환원반응의 속도와 메카니즘

  • Chang-Su Kim (Department of Chemistry, Taegu University) ;
  • Woo-Sik Lee (Department of Chemistry, Taegu University)
  • 김창수 (大邱大學敎 師範大學 化學敎育科) ;
  • 이우식 (大邱大學敎 師範大學 化學敎育科)
  • Published : 1986.10.20
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Abstract

The reduction of $VO_2^+$ ion by ethanol in sulfuric acid leads to the formation of vanadyl sulfate. Spectrophotometric measurements on the solution containing products, vanadyl sulfate, are also reported. Kinetic studies on reduction of $VO_2^+$ by ethanol have been carried out at 35${\circ}C$ and 50${\circ}C$. The reaction mechanism for reduction of $VO_2^+$ is discussed.

황산용액에서 에탄올에 의한 $VO_2^+$이온을 환원시키면 황산바나딜(IV)가 생성된다. 생성물 VOS$O_4$를 포함하는 용액에 대한 분광학적 결과가 보고된다. 에탄올에 의한 $VO_2^+$의 환원에 대한 속도론적 연구는 35${\circ}C$와 50${\circ}C$에서 행하여 졌다. $VO_2^+$의 환원반응메카니즘이 논의되었다.

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References

  1. J. Am. Chem. Soc. v.96 K.B. Wiberg;S.K. Mukherjee
  2. J. Org. Chem. v.35 R. Ratcliffe;R. Rodehorst
  3. J. Am. Chem. Soc. v.92 P.M. Nave;W.S. Trahanovsky
  4. J. Am. Chem. Soc. v.75 W.A. Mosher;D.M. Preiss
  5. J. Am. Chem. Soc. v.85 R.G. Linck;Taube
  6. Inorg. Chem. v.24 R.F. Johnston;R. A. Holwerda
  7. Structural Inorganic Chemistry A.F. Wells
  8. J. Am. Chem. Soc. v.90 C.J. Ballhousen;B.F. Djurinskij;K.J. Watson
  9. Inorg. Chem. v.2 J.C. Evans
  10. Inorg. Syn. v.5 R.A. Rowe;M.M. Jones
  11. Inorg. Chem. v.22 R.C. Thompson
  12. J. Phys. Chem. v.89 J.D. Rush;B.H.J. Bielski
  13. The Study of Kinetics and Mechanism of Reactions of Transition Metal Complexes R.G. Wilkins
  14. The Merck Index M. Windholz;M. Windholz(ed.)
  15. The Synthesis and Characterization of Inorganic Compounds W.L. Jolly
  16. Chem. Rev. v.65 J. Selbin
  17. Inorg. Chem. v.16 J.P. Birk
  18. Chem. Rev. v.71 J.O. Hill;I.G. Worsley;L.G. Helper
  19. Comprehensive Inorganic Chemistry v.3 R.J.H. Clark;J.C. Bailer, JR.(Ed.)