Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis and Characterization of New Organotin (IV)-phenylenebisdithiocarbamate Complexes

  • Lee, Won-Ho (Inorganic Chemistry Lab., Korea Advanced Institute of Science & Technology) ;
  • Jung, Ok-Sang (Inorganic Chemistry Lab., Korea Advanced Institute of Science & Technology) ;
  • Sohn, Youn-Soo (Inorganic Chemistry Lab., Korea Advanced Institute of Science & Technology) ;
  • Kim, Poong-Zag (Chemical Analysis Lab., Korea Research Institute of Chemical Technology)
  • Published : 1986.12.20
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Abstract

New di- and triorganotin(IV) complexes of meta- and para-phenylenebisdithiocarbamate(m- and p-pbdtc) have been synthesized and characterized by means of chemical analysis, mass spectrometry, and IR spectroscopy. The reaction of the m-pbdtc ligand with diorganotin(IV) halides resulted in 1:1 products, $R_2Sn{\cdot}m$-pbdtc (R = Me, Cy, n-Bu) of dimeric nature whereas the p-pbdtc ligand led to an oligomeric or polymeric structure. The pbdtc ligands were also reacted with triorganotin(IV) halides to form monomeric complexes, $(R_3Sn)_2{\cdot}pbdtc.$ The tin coordination chemistry of these complexes were also discussed in terms of Sn-C and Sn-S bonding modes.

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