Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

Absolute Configuration of p-Substituted Benzoates of Panaxynol

  • Shim, Sang-Chul (Department of Chemistry, The Korea Advanced Institute of Science and Technology) ;
  • Koh, Hun-Yeong (Department of Chemistry, The Korea Advanced Institute of Science and Technology) ;
  • Chang, Suk-Ku (Department of Chemistry, The Korea Advanced Institute of Science and Technology) ;
  • Moon, Soon-Ku (Department of Chemistry, Dongguk University) ;
  • Min, Tae-Jin (Department of Chemistry, Dongguk University)
  • Published : 1986.04.20
Download PDF
⟨ Previous Next ⟩

Abstract

Exciton chirality method was applied for the determination of absolute configuration of panaxynol, a poly-yne compound from Panax ginseng roots for the first time. The circular dichroic spectra of panaxynol benzoates show the negative chirality at ${\lambda}_{ext}$, indicating the S configuration of C-3 chiral center.

Keywords

References

  1. J. Pharmac. Soc. Japan v.84 M. Takahashi;M. Yoshikura
  2. Phytochem v.19 J. Poplawski;J.T. Wrobel;T. Glinka
  3. Phytochem. v.19 Z. Dabrowski;J.T. Wrobel;K. Wojtasiewicz
  4. Phytochem. v.22 S.C. Shim;H.Y. Koh;B.H. Han
  5. Bull. Korean Chem. Soc. v.4 S.C. Shim;H.Y. Koh;B.H. Han
  6. J. Amer. Chem. Soc. v.104 N.C. Gonnella;K. Nakanishi;V.S. Martin;K.B. Sharpless
  7. J. Amer. Chem. Soc. v.102 N. Harada;Y. Tamai;Y. Takuyama;H. Uda
  8. J. Amer. Chem. Soc. v.100 N. Harada;H. Uda

Cited by

  1. Biosynthesis of Panaxynol and Panaxydol in Panax ginseng vol.18, pp.7, 1986, https://doi.org/10.3390/molecules18077686